Nano-SbCl5/SiO2 as an Efficient Catalyst for One-Pot Synthesis of 2, 4, 5-Trisubstituted Imidazoles Under Solvent- Free Condition

نویسندگان

  • A. Bamoniri Department of Organic Chemistry, Faculty of Chemistry, University of Kashan, 51167 Kashan, I. R. Iran.
  • S. Rohani Department of Organic Chemistry, Faculty of Chemistry, University of Kashan, 51167 Kashan, I. R. Iran.
چکیده مقاله:

A general synthetic route to the synthesis of imidazoles has been developed using nano SbCl5/SiO2 under solvent-free conditions. The multi-component reactions of aldehydes, benzil and ammonium acetate were carried out to afford some trisubstituted imidazole derivatives. This method provides several advantages like simple work-up, environmentally benign, and shorter reaction times along with high yields. The mentioned nano catalyst was investigated by SEM, TEM and XRD. Meanwhile, structures of trisubstituted imidazoles were elucidated by FT-IR, 1 H NMR and 13 C NMR spectra.

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nano-sbcl5/sio2 as an efficient catalyst for one-pot synthesis of 2, 4, 5-trisubstituted imidazoles under solvent- free condition

a general synthetic route to the synthesis of imidazoles has been developed using nano sbcl5/sio2 under solvent-free conditions. the multi-component reactions of aldehydes, benzil and ammonium acetate were carried out to afford some trisubstituted imidazole derivatives. this method provides several advantages like simple work-up, environmentally benign, and shorter reaction times along with hig...

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عنوان ژورنال

دوره 2  شماره 2

صفحات  221- 226

تاریخ انتشار 2012-06-01

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